Alternatives to methyl bromide for durables and timber european. Workers health centre has many reported cases of exposure to methyl bromide in warehousing and retail workers that cause acute skin irritation, inflammation and respiratory distress. However, any release of methyl bromide or methyl bromide in a mixture of methyl bromide chloropicrin that exceeds the pound rq for methyl bromide within a 24hour period must be reported to the national response center at 18004248802, and any other applicable federal, state, and local emergency agencies. Methyl bromide bromomethane published by the world health organization for the international programme on chemical safety a collaborative programme of the united nations environment programme, the. Calculate concentration, c, of methyl bromide in the air volume sampled, v l. Pn10462 version 3 last updated march 2015 methyl bromide health monitoring guidelines page 4 of 7 absorptionexcretion pharmacology methyl bromide is a colourless, nonflammable gas with no taste or odour at low concentrations odour threshold 80 mgm3. About 1,000 human poisoning incidents caused by methyl bromide exposure have been documented, with effects ranging from skin and eye irritation to death. For commodity fumigations with methyl bromide the agency generally sets tolerances based on residue levels 24 hours after completion of fumigation.
When fighting fires involving methyl bromide, wear safety boots, nonflammable overalls, gloves, hat, goggles and selfcontained breathing apparatus. Methyl bromide is used as a fumigant and pesticide. The main sources of information for this fact sheet are epas. Methyl bromide is used in new zealand for the eradication of quarantine pests from import and export cargo. This issue issue 2, dated 11596 of method 2520 was further revised to account for the effect of humidity and to. Other names for bromomethane are methyl bromide, monobromomethane, and methyl fume. Trace amounts of methyl bromide have been detected in drinking water. All persons working with methyl bromide must be knowledgeable about the haznrcs, and. Methyl methyl bromide bromide emergency emergency response.
Other companies are charging thousands of dollars to set up accounts and give you access to their msds online database. Methyl bromide, labeled with a danger signal word, is an extremely toxic vapor. Methyl bromide in a steel tank reacted with an aluminum tube part of the level gauge producing methyl aluminum bromide. Cdc niosh pocket guide to chemical hazards methyl bromide. Managing risks of methyl bromide exposure when unpacking. Central nervous system additional data stimulants such as epinephrine may induce ventricular fibrillation. In doing so, greater than 98 per cent of the methyl bromide is consumed in the reaction process. All methyl bromide fumigations must be carried out by a licensed fumigator. The insecticidal value of methyl bromide was first reported by le goupil 1932 in. Safety data sheet creation date 16nov2010 revision date 19jan2018 revision number 4 1. Methyl bromide, also called bromomethane, a colourless, nonflammable, highly toxic gas readily liquefied belonging to the family of organic halogen compounds. Inhalation of 6 mgl for 10 to 20 hours, or 30 mgl for 1. Firstaid measures general advice show this safety data sheet to the doctor in attendance. First aid measures as this product is a gas, refer to the inhalation section.
Methods and materials for containment stop leak if you can do so without risk. With the cas registry number 74839, it is also named as dl methylbromide. Scopolamine methyl bromide, hyoscine methyl bromide, methscopolamine bromide empirical formula hill notation. Methyl bromide information biosecurity new zealand. Methyl bromide department of agriculture, water and the. Methyl bromide is a fumigant used to control pests in agriculture and shipping.
The refrigerated samples had an average recovery of 99. Sds of methyl bromide, safety data sheets, cas 74839. The wide transboundary movement of methyl bromide and products treated with methyl bromide make it especially appropriate for regulatory analysis. Obtain material safety data sheets msds for all hazardous substances from the. Methyl bromide phaseout of ozonedepleting substances ods. It is a colorless, nonflammable gas with no distinct smell. Disclaimer the sds samples above are collected from the internet by chemblink and displayed here for the tutorial purpose only. Keep cylinders cool by spraying with water until well after fire is out.
Methyl bromide is used in new zealand for the eradication of quarantine pests from import and export. It was used extensively as a pesticide until being phased out by most countries in the early 2000s. Bromomethane, commonly known as methyl bromide, is an organobromine compound with formula c h 3 br. The air concentration level is measured by a direct reading detection device, such as a mathesonkitagawa, draeger, or sensidyne. Methyl bromide, a colourless, nonflammable, highly toxic gas readily liquefied belonging to the family of organic halogen compounds.
However, any release of methyl bromide or methyl bromide in a mixture of methyl bromidechloropicrin that exceeds the pound rq for methyl bromide within a 24hour period must be reported to the national response center at 18004248802, and any other applicable federal, state, and local emergency agencies. The health and safety of our customers is always our top priority. Methyl bromide is a highly hazardous material and should be used only by individuals trained in its proper use. Obtain material safety data sheets msds for all hazardous substances from the manufacturers and. Epa, pesticide product label, methyl bromide 100, 06. Further, residues of methyl bromide in the cottonseed will be very low, as the residues will largely dissipate after fumigation, especially given the time needed to ship cottonseed to the united states. Methyl bromide is a colorless, volatile liquid or gas with a. Form of exposure permissible concentration basis bromomethane 74839 twa 1 ppm acgih c 20 ppm 80 mgm3 osha z1 twa 5 ppm. The methyl bromide is an organic compound with the formula ch 3 br. Using methyl bromide department of agriculture, water and.
Methyl bromide phaseout of ozonedepleting substances. Identification product name methylmagnesium bromide, 1m solution in thf. Can give flammable products if mixed with potassium hydroxide, sodium hydroxide and other strong bases. Epa, pesticide product label, methyl bromide 100, 06242002. This fact sheet is a summary source of information of all potential. Official use of methyl bromid e pdf methyl bromide is a colourless, odourless, nonflammable and non explosive gas under ordinary. Methyl bromide is introduced into an industrial process in order to synthesise, in combination with other chemicals, a new compound. It has a tetrahedral shape and it is a recognized ozonedepleting chemical.
Methyl bromide labels table 1 summarizes the differences between existing methyl bromide mb labels and mb manufactured after october 1, 2016. Methyl bromide bromomethane boston chemical data corp. Methyl bromide 2520 wikisource, the free online library. This colorless, odorless, nonflammable gas is produced both industrially and biologically. Before using, read and follow all label precautions and directions, including the manual for safe handling of methyl bromide products no. Table 1 mb label comparison existing mb labels instructions 2016 mb labels instructions 1. There was migration of the methyl bromide with time, with the amounts found on the back section of the tubes increasing from 5% to 11. Methyl bromide mb has a number of desirable features as a fumigant for durable. While it still remains a useful tool at the border, it is an ozone depleting substance and efforts are. Methyl bromide is a highly effective fumigant used to protect the biosecurity interests of australia and other nations across the world.
Beginning january 1, 2005, production and use of methyl bromide will stop in the united states, except for emergency and critical uses 5. Detection of methyl bromide in environmental samples, as determined by niosh. Under the montreal protocol on substances that deplete the ozone layer, methyl bromide can only be used for a nonquarantine and preshipment application if a critical use exemption has been approved by the. Your new online msds binder is a place for you to store the material safety data sheets you need to deploy. One hundred percent control of fruit fly eggs and larvae in treated. At the same time, methyl bromide is manufactured and used in other countries, and some other nations require food from the u. It also occurs naturally in small amounts in the ocean where it is formed, probably by algae and kelp. Methyl bromide bromomethane published by the world health organization for the international programme on chemical safety a collaborative programme of the united nations environment programme, the international labour organisation, and. Methyl bromide quarantine fumigant sds cardinal professional. The acceptable air concentration level for persons exposed to methyl bromide is 5 ppm 20 mgm3. The main sources of information for this fact sheet are epas integrated risk information system iris.
Methyl bromide is also used as methylating agent, a refrigerant, a fire extinguishing agent, a solvent in. The main breakdown product of methyl bromide the bromide ion can be measured in blood samples. Nptn general fact sheets are designed to answer questions. For more detailed information, refer to the treatment manual. The methyl bromide is a recognized ozonedepleting chemical. Import data and price of methyl bromide under hs code 3808. Please call npic with any questions you have about pesticides at. Besides, it is colourless gas with a chloroformlike odour.
In humans, methyl bromide is readily absorbed through the lungs. Section 1 identification of the material and supplier. Date hs code description origin country port of discharge unit quantity value inr per unit inr oct 03 2016. Chloropicrin is phytotoxic and is likely to cause damage to any living plant. It is used as a fumigant against insects and rodents in food, tobacco, and nursery stock. Method 2520 for methyl bromide, issued in august 1990 2, was based on method s372 5. A case in which a potentially exposed person is being evaluated by healthcare workers or public health officials for poisoning by a particular chemical agent, but no specific credible threat exists. Aeration and reentry after fumigation, treated areas must be aerated until the level of methyl bromide is 5 ppm or less. Sep 30, 2015 methyl bromide quarantine fumigant, epa reg. This issue issue 2, dated 11596 of method 2520 was. Registration authority approval for the fumigation of these commodities. Material safety data sheets explore our library of material safety data sheets msds to access information about the products rentokil pest control uses in the united states. Since methyl bromide is a gas at ambient temperatures, the most significant route of exposure is inhalation.
Methyl bromide is a highly effective fumigant used to control a number of pests. Methyl bromide is incompatible with metals, dimethyl sulfoxide, ethylene oxide. Hold eyelids apart and flush eyes with plenty of water for at least 15 minutes. To avoid the risk of static discharges and gas ignition, soak contaminated clothing thoroughly with water before removing it.
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